Thermodynamics analysis of the rare earth metals and their alloys with indium in solid state
Identifieur interne : 000006 ( Russie/Analysis ); précédent : 000005; suivant : 000007Thermodynamics analysis of the rare earth metals and their alloys with indium in solid state
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Abstract
Nonlinear correlative analyses between thermodynamic and some physico-chemical properties of rare-earth metals (RE) and their alloys with indium are performed for the isostructural phases RE and REIn3. The thermodynamics values (Gibbs energies of formation, enthalpies of formation, and entropies of formation at 298 K and 775 K and standard entropies) of LnIn3 phases are calculated on the basis of calorimetry and potentiometry results. The proposed correlation between physico-chemical and thermodynamic properties agrees for all the isostructural phases REX (X are others elements of the periodic table). The resulting thermodynamic data are recommended for metallurgical handbook.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Thermodynamics analysis of the rare earth metals and their alloys with indium in solid state</title><author><name sortKey="Vassiliev, V P" uniqKey="Vassiliev V">V. P. Vassiliev</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Chemical Department, Lomonossov University</s1><s2>Moscow 119992</s2><s3>RUS</s3><sZ>1 aut.</sZ></inist:fA14><country>Russie</country><placeName><settlement type="city">Moscou</settlement><region>District fédéral central</region></placeName></affiliation></author><author><name sortKey="Benaissa, Ablazeze" uniqKey="Benaissa A">Ablazeze Benaissa</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Département des Matériaux, Faculté des Sciences de l'Ingénieur, Université M'hamed Bougara</s1><s2>Boumerdes 35000</s2><s3>DZA</s3><sZ>2 aut.</sZ></inist:fA14><country>Algérie</country><wicri:noRegion>Boumerdes 35000</wicri:noRegion></affiliation></author><author><name sortKey="Taldrik, A F" uniqKey="Taldrik A">A. F. Taldrik</name><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Institute of Superconductivity and Solid State Physics, Academician Kurchatov 1</s1><s2>Moscow 123098</s2><s3>RUS</s3><sZ>3 aut.</sZ></inist:fA14><country>Russie</country><placeName><settlement type="city">Moscou</settlement><region>District fédéral central</region></placeName></affiliation></author></titleStmt><publicationStmt><idno type="inist">13-0219067</idno><date when="2013">2013</date><idno type="stanalyst">PASCAL 13-0219067 INIST</idno><idno type="RBID">Pascal:13-0219067</idno><idno type="wicri:Area/Main/Corpus">000B68</idno><idno type="wicri:Area/Main/Repository">000317</idno><idno type="wicri:Area/Russie/Extraction">000006</idno></publicationStmt><seriesStmt><idno type="ISSN">0925-8388</idno><title level="j" type="abbreviated">J. alloys compd.</title><title level="j" type="main">Journal of alloys and compounds</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Calorimetry</term><term>Chemical properties</term><term>Entropy</term><term>Heat of formation</term><term>Indium</term><term>Non linear effect</term><term>Potentiometry</term><term>Solid state</term><term>Thermodynamic analysis</term><term>Thermodynamic properties</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Analyse thermodynamique</term><term>Indium</term><term>Effet non linéaire</term><term>Propriété chimique</term><term>Chaleur formation</term><term>Entropie</term><term>Propriété thermodynamique</term><term>Calorimétrie</term><term>Potentiométrie</term><term>Etat solide</term><term>6540G</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Nonlinear correlative analyses between thermodynamic and some physico-chemical properties of rare-earth metals (RE) and their alloys with indium are performed for the isostructural phases RE and REIn<sub>3</sub>. The thermodynamics values (Gibbs energies of formation, enthalpies of formation, and entropies of formation at 298 K and 775 K and standard entropies) of LnIn<sub>3</sub> phases are calculated on the basis of calorimetry and potentiometry results. The proposed correlation between physico-chemical and thermodynamic properties agrees for all the isostructural phases REX (X are others elements of the periodic table). The resulting thermodynamic data are recommended for metallurgical handbook.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0925-8388</s0></fA01><fA03 i2="1"><s0>J. alloys compd.</s0></fA03><fA05><s2>572</s2></fA05><fA08 i1="01" i2="1" l="ENG"><s1>Thermodynamics analysis of the rare earth metals and their alloys with indium in solid state</s1></fA08><fA11 i1="01" i2="1"><s1>VASSILIEV (V. P.)</s1></fA11><fA11 i1="02" i2="1"><s1>BENAISSA (Ablazeze)</s1></fA11><fA11 i1="03" i2="1"><s1>TALDRIK (A. 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